Jean-Luc Renaud Research Group
Jean-Luc Renaud Research Group
Previous Publications
1) Synthetic Usefulness of the Cobalt(I)-Mediated Ene Type Reaction for the Diastereoselective Construction of Bicyclo[n.3.0]derivatives.
J-L. Renaud, M. Petit, C. Aubert, M. Malacria Synlett 1997, 981.
2) Cobalt Mediated Cycloisomerization of δ Substituted ε-Acetylenic β-Ketoesters. Construction of Angular Triquinane by a Sequence Ene/Pauson-Khand Reactions.
J-L. Renaud, C. Aubert, M. Malacria Tetrahedron 1999, 55, 5113-5128.
3) Synthesis of a New Versatile Dienophile and Its Used in Highly Diastereoselective Diels-Alder Reaction
J-L. Renaud, C. Aubert, M. Malacria Tetrahedron Lett. 1999, 40, 5015-5018.
4) Palladium Catalyzed Enantioselective Alkylative Ring Opening .
M. Lautens, J.-L. Renaud, S. Hiebert J. Am. Chem. Soc. 2000, 122, 1804-1805.
5) Enantioselective Ring Opening of Aza- and Oxabicyclic Alkenes with Dimethylzinc.
M. Lautens, S. Hiebert, J.-L. Renaud Org. Lett. 2000, 2, 1971-1973.
6) Mechanistic Studies of the Palladium-Catalyzed Ring Opening of Oxabicyclic Alkene with Dialkylzinc.
M. Lautens, S. Hiebert, J.-L. Renaud J. Am. Chem. Soc. 2001, 123, 6834-6839.
7) Enantioselective Pinacol Coupling of Aldehydes Mediated and Catalyzed by Chiral Titanium Complexes
A. Bensari, J-L. Renaud, O. Riant Org. Lett. 2001, 3, 3863-3865.
8) Ruthenium-Catalyzed Enantioselective Hydrogenation of Trisubstituted Enamides Derived from 2-Tetralone and 3-Chromanone : Influence of Substitution on the
Amide Arm and the Aromatic Ring.
J. L. Renaud, P. Dupau, A-E. Hay, M. Guingouain, P. H. Dixneuf, C. Bruneau Adv. Synt. Cat. 2003, 345, 230-238.
9) Ruthenium-Bisimine : A New Catalytic System for Highly Regioselective Allylic Alkylation.
J-L. Renaud, C. Bruneau, B. Demerseman Synlett 2003, 408-410.
10) Enantioselective Hydrogenation of Isomeric β-Acetamido β-Alkylacrylates: Crucial Influence of Temperature.
T. Jerphagnon, J-L. Renaud, P. Demonchaux, A. Ferreira, C. Bruneau Tetrahedron : Asymmetry 2003, 14, 1973-1977.
11) New Ru3(CO)12 based catalysts with imidazolium salt, diimine or bis-oxazoline ligand and ruthenium-bis-oxazoline complexes for tandem isomerisation/Claisen
rearrangement of dienyl ethers. X-ray structure of [RuCl((R,R)-bis(isopropyloxazoline))p-cymene]BF4.
H. Ben Ammar, J. Le Nôtre, M. Salem, M. T. Kaddachi, L. Toupet, J-L. Renaud, C. Bruneau, P.-H. Dixneuf Eur. J. Inorg. Chem. 2003, 4055-4064.
12) Novel [Cp*(η2-bipy)(MeCN)Ru(II)][PF6] Catalysts for Regioselective Allylic Substitution and First Characterization of Dicationic [Cp*(η2-bipy)(η3-allyl)Ru(IV) ] [PF6]2 Intermediates.
M. D. Mbaye, B. Demerseman, J-L. Renaud, L. Toupet, C. Bruneau Angew. Chem. Int. Ed. 2003, 42, 5066-5068.
13) Enantioselective Hydrogenation of β-Acylamino Acrylates Catalyzed by Rhodium-Monophosphite Complexes.
T. Jerphagnon, J-L. Renaud, P. Demonchaux, A. Ferreira, C. Bruneau Adv. Synth. Catal. 2004, 346, 33-36.
14) Chiral Monodentate Phosphorus Ligands for Rhodium Catalyzed Asymmetric Hydrogenation.
T. Jerphagnon, J-L. Renaud, C. Bruneau Tetrahedron : Asymmetry 2004, 15, 2101-2111.
15) Ruthenium-Catalyzed O-Allylation of Phenols from Allylic Chlorides via Cationic [Cp*(η3-allyl)(MeCN)RuX][PF6] Complexes.
M. D. Mbaye, B. Demerseman, J-L. Renaud, L. Toupet, C. Bruneau Adv. Synth. Catal. 2004, 346, 835-841.
16) First Enantioselective Allylic Etherification with Phenols Catalyzed by Ruthenium Complexes.
M. D. Mbaye, J-L. Renaud, B. Demerseman, C. Bruneau Chem. Commun. 2004, 1870-1871.
17) Concomitant monoreduction/hydrogenation of unsaturated cyclic imides to lactams catalyzed by ruthenium complexes.
R. Aoun, J-L. Renaud, P.H. Dixneuf, C. Bruneau Angew. Chem. Int. Ed. 2005, 44, 2021.
18) Ruthenium Catalyzed Allylic Substitution of Unsymmetrical Allylic Carbonate in Ionic Liquid
C. Hubert, J-L. Renaud, B. Demerseman, C. Fischmeister, C. Bruneau J. Mol. Catal., 2005, 237, 161-164.
19) α-Diimines as Nitrogen Ligands for Ruthenium-Catalyzed Allylation Reactions and Related (Pentamethylcyclopentadienyl)Ruthenium Complexes.
M. D. Mbaye, B. Demerseman, J-L. Renaud, C. Bruneau J. Organomet. Chem., 2005, 690, 2149-2158 (sur invitation).
20) Efficient Synthesis of β-Aminoacrylates and β-Enaminones Catalyzed by Zn(OAc)2.2H2O.
R. Kaur Vohra, J-L. Renaud, C. Bruneau Collect. of Czech. Chem. Comm. 2005, 70, 1943-1952.
21) π-Allylruthenium Complexes and Ruthenium-Catalyzed Nucleophilic Substitution of Allylic Substrates.
J-L. Renaud, M. D. Mbaye, B. Demerseman, C. Bruneau Current in Organic Chemistry, 2006, 10, 115-133.
22) Allylic Alkylation and Etherification Catalyzed by in situ generated N-Heterocyclic Carbene Ruthenium Complexes.
N. Gürbüz, I. Özdemir, B. Çetinkaya, J-L. Renaud, B. Demerseman, C. Bruneau Tetrahedron Lett. 2006, 47, 535-538.
23) Synthesis and Reactivity of [Ru(Cp*)(L)(MeCN)2][PF6] (L=Ph2POMe or Ph2P o tolyl) and {Ru(Cp*)[Ph2PCH2C(tBu)=O](MeCN)][PF6] Complexes, their Involvement as Catalyst Precursors for Regioselective Allylic Substitution Reactions, and Related [Ru(Cp*)Cl(Ph2POMe)(RCHCHCH2)][PF6] η3 Allyl Ruthenium(IV) Intermediates.
B. Demerseman, J-L. Renaud, L. Toupet, C. Hubert, C. Bruneau Eur. J. Inorg. Chem. 2006, 1371-1380.
24) Pentamethylcyclopentadienyl ruthenium catalysts for regio- and enantioselective allylation of nucleophiles.
C. Bruneau, J-L. Renaud, B. Demerseman Chem. Eur. J. 2006, 12, 5178-5187.
25) (S,S,S)-Perhydroindolic Acid: Efficient Catalyst for Direct Asymmetric Aldol Reaction of Aromatic Aldehydes.
X. Tang, B. Liégault, J-L Renaud, C. Bruneau Tetrahedron : Asymmetry 2006, 17, 2187-2190.
26) Lewis Acid Catalyzed Sequential Transformations: Straightforward Preparation of Substituted Dihydropyridines.
R. Kaur Vohra, C. Bruneau, J-L. Renaud Adv. Synth. Catal. 2006, 348, 2571-2574.
27) Tertiary β-Enamino Ketones and Esters: Their Lewis Acid-Free and Lewis Acid-Catalyzed Preparation From Secondary Amines and 1,3-Diketo Compounds.
R. Kaur Vohra, J-L. Renaud, C. Bruneau Synthesis 2007, 731-738.
28) Palladium Catalyzed Synthesis of Tetralines
B. Liégault, J-L Renaud, C. Bruneau Adv. Synth. Catal. 2007, 349, 841-845.
29) Synthesis of Functional 1,4-Dihydropyridines Catalyzed by Metal-Free Brønsted Acids.
J. Moreau, A. Duboc, C. Hubert, J-P. Hurvois, J-L. Renaud Tetrahedron Lett. 2007, 48, 8647-8650.
30) Preparation of β-amino acid derivatives via enantioselective hydrogenation of β-substituted-β-acetamidoacrylates.
C. Bruneau, J-L. Renaud, T. Jerphagnon Coord. Chem. Rev. 2008, 252, 532-544.
31) Activation and functionalization of benzylic derivatives by palladium catalysts.
B. Liégault, J-L. Renaud, C. Bruneau Chem. Soc. Rev. 2008, 37, 290-299.
32) Ruthenium catalysts for selective nucleophilic allylic substitution.
C. Bruneau, J-L. Renaud, B. Demerseman Pure and Applied Chemistry 2008, 80, 861-871.
33) Synthesis of Pyrans Catalyzed by Metal-Free Brønsted Acids via a formal [3+3] cycloaddition.
C. Hubert, J. Moreau, J. Batany, A. Duboc, J-P Hurvois, J-L Renaud Adv. Synth. Catal. 2008, 350, 40-42.
34) Synthesis of New Perhydroindole Derivatives and their Application in Enantioselectivie Catalysis.
B. Liégault, X. Tang, J-L Renaud, C. Bruneau Eur. J. Org. Chem. 2008, 934-940.
35) Synthesis of imidazolidinium, 3,4,5,6 tetrahydropyrimidinium, and benzimidazolium salts, and their applications in ruthenium catalyzed allylic substitution.
S. Yasar, I. Özdemir, J.-L. Renaud, C. Bruneau Eur. J. Org. Chem. 2008, 2142-2149.
36) Iron Salts Catalyzed Synthesis of β N-Substituted Aminoacrylates.
H. Hebbache, Z. Hank, S. Boutamine, M. Meklati, C. Bruneau, J.-L. Renaud C. R. Chimie 2008, 612-619.
37) Ruthenium-Catalyzed Synthesis of Allylic Alcohols: Boronic Acids as Hydroxide Sources
A. Bouziane, M. Hélou, B. Carboni, F. Carreaux, B. Demerseman, C. Bruneau, J-L Renaud Chem. Eur. J. 2008, 14, 5630.
38) Ruthenium-catalyzed tandem allylic substitution-isomerization: a direct route to propiophenones from cinnamyl chloride derivatives
M. Hélou, J.-L. Renaud, F. Carreaux, B. Demerseman, C. Bruneau New J. Chem. 2008, 32, 929-931.
39) Highly efficient and economic synthesis of new substituted amino-bispyridyl derivatives via copper and palladium catalysis.
S. Gaillard, M. K. Elmkaddem, C. Fischmeister, C. M. Thomas, J-L. Renaud Tetrahedron Lett. 2008, 49, 3471-3474.
40) Iron-Catalyzed Hydrogenation, Hydride Transfer and Hydrosilylation: An Alternative to Precious Metal Complexes?
S. Gaillard, J-L. Renaud Chem. Sus. Chem. 2008, 1, 505-508.
41) Synthesis of New Amino- and Methylene-Bispyridines and Their Coordination Chemistry with Mg(II) and Zn(II).
Z. Zheng, M. K. Elmkaddem, C. Fischmeister, T. Roisnel, C. M. Thomas, J-F. Carpentier, J-L. Renaud New J. Chem. 2008, 32, 2150-2158.
42) Synthesis of Alkaloids of Galipea Officinalis by Alkylation of an α-Aminonitrile.
S. Shahane, F. Louafi, J. Moreau, J-P. Hurvois, J-L. Renaud, T. Roisnel Eur. J. Org. Chem. 2008, 4622-4631.
43) Pentamethylcyclopentadienyl Ruthenium Catalyzed Redox Isomerization of Allylic Alcohols into Carbonyl Compounds.
A. Bouziane, B. Carboni, C. Bruneau, F. Carreaux, J-L. Renaud Tetrahedron 2008, 64, 11745-11750.
44) Synthesis of N-functionalized 2,2’-dipyridylamine ligands, complexation to ruthenium (II) and anchoring of complexes to papain from papaya latex.
P. Haquette, B. Dumat, B. Talbi, S. Arbabi, J.-L. Renaud, G. Jaouen, M. Salmain J. Organomet. Chem. 2009, 694, 937-941 (sur invitation).
45) Hydrogenation of β-N-Substituted and β-N,N-Disubstituted Enaminoesters in the presence of Iridium(I) Catalyst.
H. Hebbache, Z. Hank, C. Bruneau, J.-L. Renaud Synthesis 2009, 2627-2633.
46) Metal-free Bronsted Acids Catalyzed Formal [3+3] Annulation. Straightforward Synthesis of Pyrans.
J. Moreau, C. Hubert, J. Batany, L. Toupet, T. Roisnel, J-P Hurvois, J-L Renaud J. Org. Chem. 2009, 74, 8963-8973.
47) Efficient synthesis of amino-pyridine derivatives by copper catalyzed amination reactions
M. K. Elmkaddem, C. Fischmeister, C. M. Thomas, J-L. Renaud Chem. Commun. 2010, 925-927.
48) A New Approach for the Enantioselective preparation of 6,8-dioxabicyclo[3.2.1]octane ring system from a three component reaction: application to the synthesis of (+)-iso-exo-brevicomin including a Ru-catalyzed isomerization step
A. Bouziane, T. Régnier, F. Carreaux, B. Carboni, C. Bruneau, J.-L. Renaud Synlett 2010, 207-210.
49) Hydrogenation of β-N-Substituted Enaminoesters in in the Presence of Ruthenium Catalysts.
H. Hebbache, T. Jerphagnon, Z. Hank, C. Bruneau, J.-L. Renaud J. Organomet. Chem. 2010, 695, 870-874.
50) Transfert Hydride in Water Catalyzed by Dipyridylamine Ruthenium Complexes.
C. Romain, S. Gaillard, M. K. Elmkaddem, L. Toupet, C. Fischmeister, C. M. Thomas, J.-L. Renaud Organometallics 2010, 29, 1992-1995.
51) Direct Amination of Aryl Halides with Ammonia.
Y. Aubin, C. Fischmeister, C. M. Thomas, J.-L. Renaud Chem. Soc. Rev. 2010, 39, 4130-4145.
52) Knölker’s Iron Complex: An Efficient in situ Generated Catalyst In Reductive Amination of Alkyl Aldehydes and Amines.
A. Pagnoux-Ozherelyeva, N. Pannetier, M. D. Mbaye, S. Gaillard, J.-L. Renaud, Angew. Chem. Int. Ed. 2012, 51, 4976-4980.
53) Ruthenium Catalyzed Redox Isomerization of Trifluoromethylated Allylic Alcohols: Mechanistic Evidence for an Enantiospecific Pathway
V. Bizet, X. Pannecoucke, J.-L. Renaud, D. Cahard Angew. Chem. Int. Ed. 2012, 51, 6467-6470.
54) New Developments in the Synthesis of Dihydropyridines (DHP’s), Dihydropyrimidines (DHPM’s) and some Pyrans Derivatives
H. T. Pham, I. Chataigner, J.-L. Renaud Current in Organic Chemistry, 2012, 16, 1754-1775
55) When phosphorus and NHC (N-Heterocyclic Carbene) meet each other.
S. Gaillard, J.-L. Renaud, Dalton Trans. 2013, 42, 7255-7270
56) Synthesis of -CF3 Ketones from Trifluoromethylated Allylic Alcohols by Ruthenium Catalyzed Redox Isomerization
V. Bizet, X. Pannecoucke, J.-L. Renaud, D. Cahard J. Fluor. Chem. 2013, 152, 56-61
57) Ruthenium-catalyzed one pot tandem isomerization–transfer hydrogenation reactions of g-CF3 allylic alcohols and β-CF3 enones.
V. Bizet, X. Pannecoucke, J.-L. Renaud, D. Cahard Adv. Synth. Catal. 2013, 355, 1394-1402
58) Straightforward Synthesis of Substituted Dibenzyl Derivatives
Clève D. Mboyi, Sylvain Gaillard, Mbaye M. Mbaye, Nicolas Pannetier, Jean-Luc Renaud. Tetrahedron, 2013, 69, 4875-4882
Dominique Cahard, Vincent Bizet, Xiaoyang Dai, Sylvain Gaillard, Jean-Luc Renaud, J. Fluor. Chem, 2013, 155, 78-82
60) Bifunctional Iron Complexes: Efficient Catalysts for C=O and C=N. Reduction in Water
Delphine S. Mérel, Margaux Elie, Jean-François Lohier, Sylvain Gaillard, Jean-Luc Renaud. ChemCatChem, 2013, 5, 2939-2945
61) Bifunctional (Cyclopentadienone)Iron tricarbonyl Complexes: Synthesis, Computational Studies and Application in Reductive Amination
Solenne Moulin, Hélène Dentel, Anastassiya Pagnoux-Ozherelyeva, Sylvain Gaillard, Albert Poater, Luigi Cavallo, Jean-François Lohier, Jean-Luc Renaud, Chem.
Eur. J., 2013, 19, 17881.
62) Iron(II)-Catalyzed [2+2+2] Cycloaddition for Pyridine Ring Construction
Vincent Richard, Mélinda Ipouck, Delphine, S. Mérel, Sylvain Gaillard, Bernhard Witulski, Richard Whitby, Jean-Luc Renaud, Chem. Commun. 2014, 50, 593-595.
63) Iridium(III) dipyridylamine complexes: Synthesis, characterization and catalytic activities in photoredox reactions
E. Sauvageot, R. Marion, F. Sguerra, A. Grimault, R. Daniellou, M. Hamel, S. Gaillard, J.-L. Renaud Org. Chem. Front. 2014, 1, 639-644.
64) Thermo- and Radioluminescent Polystyrene Based Plastic Scintillators Doped with Phosphorescent Iridium(III) Complexes
F. Sguerra, R. Marion, G. H. V. Bertrand, E. Sauvageot, R. Daniellou, J.-L. Renaud, S. Gaillard, M. Hamel J. Chem. Mater. C 2014, 2, 6125-6133.
65) NHC Copper(I) Complexes Bearing Dipyridylamine Ligands: Synthesis, Structural and Photoluminescence studies
R. Marion, F. Sguerra, F. Di Meo, E. Sauvageot, J.-F. Lohier, R. Daniellou, J.-L. Renaud, M. Linares, M. Hamel, S. Gaillard Inorg. Chem. 2014, 53, 9181-9191.
66) Iron-Catalyzed Hydrogenation of Esters to Alcohols
P. Dupau, M.-L. Tran Do, S. Gaillard, J.-L. Renaud Angew. Chem. Int. Ed. 2014, 53, 13004-13006.
67) Microwave-Assisted Synthesis of Piano-Stool Iron Complexes
A. Pagnoux-Ozherelyeva, D. Bolien, S. Gaillard, F. Peudru, J.-F. Lohier, R. J. Whitby, J.-L. Renaud J. Organomet. Chem. 2014, 774, 35-42.
68) Iron-Catalyzed Reduction of Carboxylic and Carbonic Derivatives
D. S. Mérel, M.-L. Tran Do, S. Gaillard, P. Dupau, J.-L. Renaud. Coord. Chem. Rev. 2015, 288, 50-68.
69) Highly Active Phosphine Free Bifunctional Iron Complex for Hydrogenation of Bicarbonate and Reductive Amination
T-T. Thai, D. S. Mérel, A. Poater, S. Gaillard, J.-L. Renaud, Chem. Eur. J. 2015, 21, 7066-7070.