Jean-Luc Renaud Research Group
Jean-Luc Renaud Research Group
Recent Publications
2021
Iron-catalyzed chemoselective hydride transfer reactions
S. Coufourier, D. Ndiaye, Q. G. Gaillard, L. Bettoni, N. Joly, M. D. Mbaye, A. Poater, S. Gaillard, J.-L. Renaud, Tetrahedron, 2021, 90, 132187
DOI: 10.1016/j.tet.2021.132187
Palladium-Catalyzed Domino Heck/Sulfination: Synthesis of Sulfonylated Hetero- and Carbocyclic Scaffolds Using DABCO–Bis(sulfur dioxide)
J. Bajohr, A. G. Diallo, A. White, S. Gaillard, J.-L. Renaud, M. Lautens, Org. Lett, 2021, 23, 2797-2801
DOI: 10.1021/acs.orglett.1c00716
Phosphine-Free Ruthenium Complex-Catalyzed Synthesis of Mono- or Dialkylated Acyl Hydrazides via the Borrowing Hydrogen Strategy
N. Joly, L. Bettoni, S. Gaillard, A. Poater, J.-L. Renaud, J. Org. Chem., 2021, 86, 6813-6825
DOI: 10.1021/acs.joc.1c00654
Ruthenium-Catalyzed Three-Component Alkylation: A Tandem Approach to the Synthesis of Nonsymmetric N,N-Dialkyl Acyl Hydrazides with Alcohols
L. Bettoni, N. Joly, J.-F. Lohier, S. Gaillard, A. Poater, J.-L. Renaud, Adv. Synth. Catal., 2021, in press
DOI:10.1002/adsc.202100554
2020
A phosphine-free iron complex-catalyzed synthesis of cycloalkanes via the borrowing hydrogen strategy
L. Bettoni, S. Gaillard, J.-L. Renaud, Chem. Commun., 2020, 56, 12909-12912
DOI: 10.1039/d0cc05840h
Aminomethylation of Oxabenzonorbornadienes via the Merger of Photoredox and Nickel Catalysis
A. Diallo, D. Roy, S. Gaillard, M. Lautens, J.-L. Renaud, Org. Lett., 2020, 22, 2442-2447
DOI: 10.1021/acs.orglett.0c00593
Artificial iron hydrogenase made by covalent grafting of Knölker's complex into xylanase: Application in asymmetric hydrogenation of an aryl ketone in water
K. Kariyawasam, W. Ghattas, Y. L. Santos, N. Doucet, S. Gaillard, J.-L. Renaud, F. Avenier, J.-P. Mahy, R. Ricoux, Biotechnol. Appl. Biochem., 2020, 67, 563-573
DOI: 10.1002/bab.1906
Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water
D. Ndiaye, S. Coufourier, M. D. Mbaye, S. Gaillard, J.-L. Renaud, Molecules, 2020, 25, 421-432
DOI: 10.3390/molecules25020421
Hydrogenation of CO2, Hydrogenocarbonate and Carbonate to Formate in Water using Phosphine Free Bifunctional Iron Complexes
S. Coufourier, Q. G. Gaillard, J.-F. Lohier, A. Poater, S. Gaillard, J.-L. Renaud, ACS Catal., 2020, 10, 2108-2116
DOI: 10.1021/acscatal.9b04340
Iron-Catalyzed α-Alkylation of Ketones with Secondary Alcohols: Access to β-Disubstituted Carbonyl Compounds
L. Bettoni, S. Gaillard, J.-L. Renaud, Org. Lett., 2020, 22, 2064-2069
DOI: 10.1021/acs.orglett.0c00549
Iron, Tricarbonyl‐1,4‐bis[(dimethylamino)ethyl]‐5,7‐diphenyl‐1,2,3,4‐tetrahydro‐6H ‐cyclopenta[b]pyrazin‐6‐one
J.-L. Renaud, S. Gaillard, Eros, 2020
DOI: 10.1002/047084289X.rn02333
Recent Advances in Solid-State Lighting Devices Using Transition Metal Complexes Exhibiting Thermally Activated Delayed Fluorescent Emission Mechanism
G. U. Mahoro, J. F. Cestau , J.-L. Renaud, P. B. Coto, R. D. Costa, S. Gaillard, Adv. Opt. Mater., 2020, 8, 2000260
DOI: 10.1002/adom.202000260
Solving the Challenging Synthesis of Highly Cytotoxic Silver Complexes bearing Sterically Hindered NHC Ligands with Mechanochemistry
A. Beillard, F. Quintin, J. Gatignol, P. Retailleau, J.-L. Renaud, S. Gaillard, T. X. Métro, F. Lamaty, X. Bantreil, Dalton Trans., 2020, 49, 12592-12598
DOI: 10.1039/D0DT00410C
2019
2,2'-Dipyridylamines more than just sister members of the bipyridine family. Applications and achievements in homogeneous catalysis and photoluminescent materials
S. Wang, C. Bruneau, J.-L. Renaud, S. Gaillard, C. Fischmeister, Dalton Trans., 2019, 48, 11599-11622
DOI: 10.1039/c9dt02165e
A MOF-assisted phosphine free bifunctional iron complex for the hydrogenation of carbon dioxide, sodium bicarbonate and carbonate to formate
S. Coufourier, S. Gaillard, G. Clet, C. Serre, M. Daturi, J.-L. Renaud, Chem. Commun., 2019, 55, 4977-4980
DOI: 10.1039/c8cc09771b
Cytotoxicity of cationic NHC copper(I) complexes coordinated to 2,2'-bis-pyridyl ligands
M. Elie, G. U. Mahoro, E. Duverger, J.-L. Renaud, R. Daniellou, S. Gaillard, J. Organomet. Chem., 2019, 893, 21-31
DOI: 10.1016/j.jorganchem.2019.04.003
Iron-Catalyzed Tandem Three-Component Alkylation: Access to α-Methylated Substituted Ketones
L. Bettoni, C. Seck, M. D. Mbaye, S. Gaillard, J.-L. Renaud, Org. Lett., 2019, 21, 3057-3061
DOI: 10.1021/acs.orglett.9b00630
Room-Temperature Chemoselective Reductive Alkylation of Amines Catalyzed by a Well-Defined Iron(II) Complex Using Hydrogen
A. Lator, Q. G. Gaillard, D. Merel, J.-F. Lohier, S. Gaillard, A. Poater, J.-L. Renaud, J. Org. Chem., 2019, 84, 6813-6829
DOI: 10.1021/acs.joc.9b00581
Iron-Catalyzed β-Alkylation of Alcohols
L. Bettoni, S. Gaillard, J.-L. Renaud, Org. Lett., 2019, 21, 8404-8408
DOI: 10.1021/acs.orglett.9b03171
2018
Bifunctional Iron Complexes Catalyzed Alkylation of Indoles
C. Seck, M. D. Mbaye, S. Gaillard, J.-L. Renaud, Adv. Synth. Catal., 2018, 360, 4640-4645
DOI: 10.1002/adsc.201800924
Iron-Catalyzed Chemoselective Reduction of α,β-Unsaturated Ketones
A. Lator, S. Gaillard, A. Poater, J.-L. Renaud, Chem. Eur. J., 2018, 24, 5770-5774
DOI: 10.1002/chem.201800995
N -Heterocyclic carbene transition metal complexes in light emitting devices
M. Elie, J.-L. Renaud, S. Gaillard, Polyhedron, 2018, 140, 158-168
DOI: 10.1016/j.poly.2017.11.045
Rationalizing Fabrication and Design Toward Highly Efficient and Stable Blue Light-Emitting Electrochemical Cells Based on NHC Copper(I) Complexes
M. Weber, E. Fresta, M. Elie, M. Miehlich, J.-L Renaud, K. Meyer, S. Gaillard, R. Costa, Adv. Funct. Mater, 2018, 28, 1707423-1707436
DOI: 10.1002/adfm.201707423
Well-Defined Phosphine-Free Iron-Catalyzed N -Ethylation and N -Methylation of Amines with Ethanol and Methanol
A. Lator, S. Gaillard, A. Poater, J.-L. Renaud, Org. Lett., 2018, 20, 5985-5990
DOI: 10.1021/acs.orglett.8b02080
2017
Alkylation of Ketones Catalyzed by Bifunctional Iron Complexes: From Mechanistic Understanding to Application
C. Seck, M. D. Mbaye, S. Coufourier, A. Lator, J.-F. Lohier, A. Poater, T. R. Ward, S. Gaillard, J.-L. Renaud ChemCatChem, 2017, 9, 4410-4416
DOI: 10.1107/S241431461700462X
Antipseudomonal activity enhancement of luminescent iridium (III) dipyridylamine complexes under visible blue light
E. Sauvageot, M. Elie, S. Gaillard, R. Daniellou, P. Fechter, I. Schalk, V. Gasser, J.-L. Renaud, G. Mislin, Metallomics, 2017, 9, 1820-1827
DOI: 10.1039/c7mt00262a
Large irradiation doses can improve the fast neutron/gamma discriminating capability of plastic scintillators
E. Montbardon, M.-N. Amiot, D. Tromson, S. Gaillard, C. Frangwille, R. Woo, G. H. V. Bertrand, R. B. Pansu, J.-L. Renaud, M. Hamel, Phys. Chem. Chem. Phys., 2017,19, 28105-28115
DOI: 10.1039/C7CP04034B
Role of the Bridging Group in Bis-Pyridyl Ligands: Enhancing Both the Photo- and Electroluminescent Features of Cationic (IPr)Cu I Complexes
M. Elie, M. D. Weber, F. D. Meo, F. Sguerra, J.-F. Lohier, R. B. Pansu, J.-L. Renaud, M. Hamel, M. Linares, R. D. Costa, S. Gaillard, Chem. Eur. J., 2017, 23, 16328-16337
DOI: 10.1002/chem.201703270
Structural Variation of Carbazole Derivatives for Plastic Scintillation Applications
E. Montbarbon, F. Sguerra, G. H. V. Bertrand, S. Gaillard, J.-L. Renaud, R. B. Pansu, M. Hamel, ChemPhotoChem, 2017, 1, 451-458
DOI: 10.1002/cptc.201700055
Zinc mediated straightforward access to diacylpyrroles
D. Faye, M. D. Mbaye, S. Coufourier, A. Lator, S. Y. Dieng, J.-L. Renaud, S. Gaillard, C. R. Chim., 2017, 20, 492-499
DOI : 10.1016/j.crci.2017.01.003
2016
Achiral bifunctionnal (cyclopentadienone)iron tricarbonyl complexes embedded in streptavidin : Application in asymmetric hydrogenation
Mérel, D. S., Gaillard, S., Ward, T. R., Renaud, J.-L. Catal. Lett., 2016, 146, 564-569
DOI : 10.1007/s10562-015-1681-6
Designing NHC-Copper(I) Dipyridylamine Complexes for Blue Light-Emitting Electrochemical Cells
Elie, M., Sguerra, F., Di Meo, F., Weber, M. D., Marion, R., Grimault, A., Lohier, J.-F., Stallivieri, A., Brosseau, A., Pansu, R. B., Renaud, J.-L., Linares, M., Hamel, M., Costa, R. D., Gaillard, S. ACS Appl. Mater. & Interfaces, 2016, 8, 14678-14691
DOI: 10.1021/acsmi.6b04647
Iridium complexes inhibit tumor necrosis factor-alpha by utilizing light and mixed ligands
Sauvageot, E.; Lafite, P.; Duverger, E.; Marion, R.; Hamel, M.; Gaillard S.; Renaud, J.-L.; Daniellou, R. J. Organomet. Chem., 2016, 808, 122-127
DOI: 10.1016/j.jorganchem.2016.02.001
Recent Advances in Iron- and Cobalt-Complex-Catalyzed Tandem/Consecutive Processes Involving Hydrogenation
Renaud, J.-L.; Gaillard, S. Synthesis, 2016, 3659-3683
DOI: 10.1055/s-0035-1562791
2015
Asymmetric isomerization of allylic alcohols
D. Cahard, S. Gaillard, J.-L. Renaud Tetrahedron Lett., 2015, 56, 6159-6169
DOI: 10.1016/j.tetlet.2015.09.098
Highly Active Phosphine Free Bifunctional Iron Complex for Hydrogenation of Bicarbonate and Reductive Amination
T-T. Thai, D. S. Mérel, A. Poater, S. Gaillard, J.-L. Renaud, Chem. Eur. J., 2015, 21, 7066-7070
DOI: 10.1002/chem.201500720
Iron-Catalyzed Carbon–Nitrogen, Carbon–Phosphorus, and Carbon–Sulfur Bond Formation and Cyclization Reactions
J.-L. Renaud, S. Gaillard, Top. Orgamet. Chem., 2015, 50, 83-144
DOI: 10.1007/3418_2015_103
Iron-Catalyzed Reduction of Carboxylic and Carbonic Derivatives
D. S. Mérel, M.-L. Tran Do, S. Gaillard, P. Dupau, J.-L. Renaud. Coord. Chem. Rev., 2015, 288, 50-68
DOI: 10.1016/j.ccr.2015.01.008
2014
Iridium(III) dipyridylamine complexes: Synthesis, characterization and catalytic activities in photoredox reactions
E. Sauvageot, R. Marion, F. Sguerra, A. Grimault, R. Daniellou, M. Hamel, S. Gaillard, J.-L. Renaud Org. Chem. Front., 2014, 1, 639-644
DOI: 10.1039/c4qo00059e
Iron(II)-Catalyzed [2+2+2] Cycloaddition for Pyridine Ring Construction
Vincent Richard, Mélinda Ipouck, Delphine, S. Mérel, Sylvain Gaillard, Bernhard Witulski, Richard Whitby, Jean-Luc Renaud, Chem. Commun., 2014, 50, 593-595
DOI: 10.1039/c3cc47700b
Iron-Catalyzed Hydrogenation of Esters to Alcohols
P. Dupau, M.-L. Tran Do, S. Gaillard, J.-L. Renaud Angew. Chem. Int. Ed., 2014, 53, 13004-13006
DOI: 10.1002/anie.201407613 et 10.1002/ange.201407613
Microwave Irradiation and Flow Chemistry for a Straightforward Synthesis of Piano-Stool Iron Complexes
A. Pagnoux-Ozherelyeva, D. Bolien, S. Gaillard, F. Peudru, J.-F. Lohier, R. J. Whitby, J.-L. Renaud J. Organomet. Chem., 2014, 774, 35-42
DOI: 10.1016/j.jorganchem.2014.09.031
NHC Copper(I) Complexes Bearing Dipyridylamine Ligands: Synthesis, Structural and Photoluminescence studies
R. Marion, F. Sguerra, F. Di Meo, E. Sauvageot, J.-F. Lohier, R. Daniellou, J.-L. Renaud, M. Linares, M. Hamel, S. Gaillard Inorg. Chem., 2014, 53, 9181-9191
DOI: 10.1021/ic501230m
Thermo- and Radioluminescent Polystyrene Based Plastic Scintillators Doped with Phosphorescent Iridium(III) Complexes
F. Sguerra, R. Marion, G. H. V. Bertrand, E. Sauvageot, R. Daniellou, J.-L. Renaud, S. Gaillard, M. Hamel J. Chem. Mater. C, 2014, 2, 6125-6133
DOI: 10.1039/c4tc00772g
2013
Bifunctional (Cyclopentadienone)Iron tricarbonyl Complexes: Synthesis, Computational Studies and Application in Reductive Amination
S. Moulin, H. Dentel, An. Pagnoux-Ozherelyeva, S. Gaillard, A. Poater, L. Cavallo, J.-F. Lohier, J.-L. Renaud, Chem. Eur. J., 2013, 19, 17881
DOI: 10.1002/chem.201302432
Bifunctional Iron Complexes: Efficient Catalysts for C=O and C=N. Reduction in Water
D. S. Mérel, M. Elie, J.-F. Lohier, S. Gaillard, J.-L. Renaud. ChemCatChem, 2013, 5, 2939-2945
DOI: 10.1002/cctc.201300325
Iron (II) complexes are suitable catalysts for the isomerization of trifluoromethylated allylic alcohols. Synthesis of trifluoromethylated dihydrochalcones
D. Cahard, V. Bizet, X. Dai, S. Gaillard, J.-L. Renaud, J. Fluor. Chem, 2013, 155, 78-82
DOI: 10.1016/j.jfluchem.201305028
Ruthenium-catalyzed one pot tandem isomerization–transfer hydrogenation reactions of g-CF3 allylic alcohols and β-CF3 enones
V. Bizet, X. Pannecoucke, J.-L. Renaud, D. Cahard, Adv. Synth. Catal., 2013, 355, 1394-1402
DOI: 10.1002/adsc.201300119
Straightforward Synthesis of Substituted Dibenzyl Derivatives
C. D. Mboyi, S. Gaillard, M. M. Mbaye, N. Pannetier, J.-L. Renaud., Tetrahedron, 2013, 69, 4875-4882
DOI: 10.1016/j.tet.201305073
Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization
V. Bizet, X. Pannecoucke, J.-L. Renaud, D. Cahard, J. Fluor. Chem, 2013, 152, 56-61
DOI: 10.1016/j.jfluchem.201301004
When phosphorus and NHC (N-Heterocyclic Carbene) meet each other
S. Gaillard, J.-L. Renaud, Dalton Trans., 2013, 42, 7255-7270
2012
New Approaches to Nitrogen Containing Heterocycles: Enantioselective Organocatalyzed Synthesis of Dihydropyridines (DHP's), Quinolizidine Derivatives and Dihydropyrimidines (DHPM's)
H. T. Pham, I. Chataigner, J.-L. Renaud, Curr. Org. Chem., 2012, 16, 1754-1775
DOI: 10.2174/138527212802651322
Knolker's Iron Complex: An Efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines
A. Pagnoux-Ozherelyeva, N. Pannetier, M. D. Mbaye, S. Gaillard, J.-L. Renaud, Ang. Chem. Int. Ed., 2012, 51, 4976-4980
DOI: 10.1002/anie.201201360
Ruthenium-Catalyzed Redox Isomerization of Trifluoromethylated Allylic Alcohols: Mechanistic Evidence for an Enantiospecific Pathway
V. Bizet, X. Pannecoucke, J.-L. Renaud, D. Cahard, Ang. Chem. Int. Ed., 2012, 51, 6467-6470
DOI: 10.1002/anie.201200827