Jean-Luc Renaud Research Group
Jean-Luc Renaud Research Group
Publications Dr. Sylvain Gaillard
48) Recent Advances in Iron- and Cobalt-Complex-Catalyzed Tandem/Consecutive Processes Involving Hydrogenation
Renaud, J.-L.; Gaillard, S. Synthesis, 2016, in press
47) Designing NHC-Copper(I) Dipyridylamine Complexes for Blue Light-Emitting Electrochemical Cells
Elie, M.; Sguerra, F.; Di Meo, F.; Weber, M. D.; Marion, R.; Grimault, A.; Lohier, J.-F.; Stallivieri, A.; Brosseau, A.; Pansu, R. B.; Renaud, J.-L.; Linares, M.; Hamel, M.; Costa, R. D.; Gaillard, S. ACS Appl. Mater. & Interfaces 2016, 8, 14678-14691.
46) Iridium complexes inhibit tumor necrosis factor-alpha by utilizing light and mixed ligands
Sauvageot, E.; Lafite, P.; Duverger, E.; Marion, R.; Hamel, M.; Gaillard S.; Renaud, J.-L.; Daniellou, R. J. Organomet. Chem. 2016, 808, 122-127.
45) Achiral bifunctionnal (cyclopentadienone)iron tricarbonyl complexes embedded in streptavidin : Application in asymmetric hydrogenation
Mérel, D. S.; Gaillard, S.; Ward, T. R.; Renaud, J.-L. Catal. Lett. 2016, 146, 564-569.
44) Asymmetric isomerization of allylic alcohols
Cahard, D.; Gaillard, S.; Renaud, J.-L. Tetrahedron Lett. 2015, 56, 6159-6169.
43) Competitive Gold-Promoted Meyer–Schuster and oxy-Cope Rearrangements of 3-Acyloxy-1,5-enynes: Selective Catalysis for the Synthesis of (+)-(S)-g-Ionone and ()- (2S,6R)-cis-g-Irone
Bugoni, S.; Merlini, V.; Porta, A.; Gaillard, S.; Zanoni, G.; Nolan, S. P.; Vidari G. Chem. Eur. J. 2015, 21, 14068-14074.
42) Highly Active Phosphine Free Bifunctional Iron Complex for Hydrogenation of Bicarbonate and Reductive Amination
T-T. Thai, D. S. Mérel, A. Poater, S. Gaillard, J.-L. Renaud, Chem. Eur. J. 2015, 21, 7066-7070.
41) Iron-catalyzed carbon-nitrogen, carbon-phosphorus, and carbon-sulfur bond formation and cyclization reactions
Renaud, J.-L.; Gaillard, S. Top. Organomet. Chem. 2015, 50, 83-144.
40) Iron-catalyzed reduction of carboxylic and carbonic acid derivatives.
Mérel, D. S.; Tran Do, M. L.; Gaillard, S.; Dupau, P.; Renaud, J.-L. Coord. Chem. Rev. 2015, 288, 50-58.
39) Microwave irradiation and flow chemistry for straightforward synthesis of piano-stool iron complexes.
Pagnoux-Ozherelyeva A.; Bolien, D.; Gaillard, S.; Peudru, F.; Lohier, J.-F.; Whitby, R. J.; Renaud, J.-L. J. Organomet. Chem. 2014, 774, 35-42.
38) Iron-catalyzed hydrogenation of esters to alcohol.
Dupau, P.; Tran Do M.-L.; Gaillard S.; Renaud, J.-L. Angew Chem. Int. Ed. 2014, 53, 13004-13006.
37) Thermo- and radioluminescent polystyrene based plastic scintillators doped with phosphorescent iridium(III) complexes.
Sguerra, F.; Marion, R.; Bertrand, H. V.; Coulon, R.; Sauvageot, E.; Daniellou, R.; Renaud, J.-L.; Gaillard, S.; Hamel, M. J. Mater. Chem. C 2014, 2, 6125-6133.
36) NHC copper(I) complexes bearing dipyridylamine ligands: synthesis, structural and photoluminescence studies.
Marion, R.; Sguerra, F.; Sauvageot, E.; Lohier, J.-F.; Daniellou, R.; Renaud, J.-L.; Linares, M.; Hamel, M.; Gaillard S. Inorg. Chem. 2014, 53, 9181-9191.
35) Iridium(III) dipyridylamine complexes: Synthesis, characterization and catalytic activities in photoredox reactions. (Invitation)
Sauvageot, E.; Marion, R.; Sguerra, F.; Grimault, A.; Daniellou, R.; Hamel, M.; Gaillard, S.; Renaud J.-L. Org. Chem. Front. 2014, 639-644.
34) Iron(II)-Catalyzed [2+2+2] Cycloaddition for Pyridine Ring Construction
Richard, V.; Ipouck, M.; Mérel, D. S.; Gaillard, S.; Witulski, B.; Whitby, R.; Renaud, J.-L. Chem. Commun. 2014, 50, 593-595.
33) Bifunctional (Cyclopentadienone)Iron tricarbonyl Complexes: Synthesis, Computational Studies and Application in Reductive Amination
Moulin, S. Dentel, H.; Pagnoux-Ozherelyeva, A.; Gaillard, S.; Poater, A.; Cavallo, L.; Lohier, J.-F.; Renaud, J.-L. Chem. Eur. J. 2013, 19, 17881-17890.
32) Bifunctional Iron Complexes: Efficient Catalysts for C=O and C=N. Reduction in Water
Mérel, D. S.; Elie, M.; Lohier, J.-F.; Gaillard, S.; Renaud, J.-L. ChemCatChem, 2013, 5, 2939-2945.
31) Straightforward Synthesis of Substituted Dibenzyl Derivatives
Mboyi, C. D.; Gaillard, S. Mbaye, M. M.; Pannetier, N.; Renaud, J.-L. Tetrahedron, 2013, 69, 4875-4882.
30) Iron (II) complexes are suitable catalysts for the isomerization of trifluoromethylated allylic alcohols. Synthesis of trifluoromethylated dihydrochalcones
Cahard, D.; Bizet, V.; Dai, X.; Gaillard, S.; Renaud, J.-L. J. Fluor. Chem, 2013, 355, 1394-1402.
29) When phosphorus and NHC (N-Heterocyclic Carbene) meet each other
Gaillard, S.; Renaud, J.-L. Dalton Trans. 2013, 42, 7255-7266
28) Phosphate binding to the [Au(IPr)] moity: inner vs. outer sphere coordination behavior
Gaillard, S.; Rix, D.; Slawin, A. M. Z.; Lacour, J.; Nolan, S. P. Dalton Trans. 2012, 41, 8235-8237.
27) Knölker’s Iron Complex : An efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines
Pagnoux-Ozherelyeva, A.; Pannetier, N.; Mbaye, D. M.; Gaillard, S.; Renaud, J.-L. Angew. Chem. Int. Ed. 2012, 51, 4975-4980.
26) Chromium, Chloro[(1R,2S)-2,3-dihydro-1-[[[2-(hydroxy-κO)-5-methyl-3-tricyclo-[3.3.1.13,7]dec-1-ylphenyl]methyl-ene]-amino-κN]-1H-indene-2-olato-(2-)-κO]
Gaillard, S.; Renaud, J.-L. EROS 2012, DOI: 10.1002/047084289X.rn01441
25) N-Heterocyclic Carbene Gold(I) and Copper(I) Complexes in C-H Bond Activation
Gaillard, S.; Cazin, C. S. J.; Nolan, S. P. Acc. Chem. Res. 2012, 45, 778-787.
24) Selectivity Switch in the Synthesis of Vinylgold(I) Intermediates
Hashmi A. S. K.; Schuster A. M.; Gaillard, S.; Cavallo L.; Poater A.; Nolan S. P. Organometallics 2011, 30, 6328-6337.
23) The role of silver additives in gold-mediated C-H functionalisation
Patrick, S. R., Boogaerts, I. I. F.; Gaillard, S., Slawin, A. M. Z., Nolan, S. P. Beilstein J. Org. Chem. 2011, 7, 892-896.
22) Polymerization of Racemic β-Butyrolactone Using Gold Catalysts: A simple Access to Biodegradable Polymers
Brulé E., Gaillard, S., Rager M.-N., Roisnel T., Guérineau V., Nolan S. P., Thomas, C. M. Organometallics 2011, 30, 2650-2653.
21) Cytotoxicity of Gold(I) N-Heterocyclic Carbene Complexes Assessed by Using Human Tumor Cell Lines
Weaver J., Gaillard, S., Toye C.; Macpherson S., Nolan, S. P., Riches A. Chem. Eur. J. 2011, 17, 6620-6624.
20) Luminescent Hyperbranched polymers: Combining thiol-yne chemistry with gold-mediated C-H bond activation
Konkolewicz, D., Gaillard, S., West, A. G., Cheng, Y. Y., Gray-Weale, A., Schmidt, T. W., Nolan, S. P., Perrier, S. Organometallics, 2011, 30, 1315-1318.
19) Gold(I)-catalyzed synthesis of furans and pyrroles via alkyne hydration
Nun, P.; Dupuy, S.; Gaillard, S.; Poater, A.; Cavallo, L.; Nolan, S. P. Catal. Sci. Technol. 2011, 1, 58-61.
18) Gold mediated synthesis of α-ionone
Merlini V., Gaillard, S., Porta A., Zanoni G., Vidari G., Nolan S. P. Tetrahedron Lett. 2011, 52, 1124-1127.
17) [{Au(IPr)}2(µ-OH)]X complexes: Synthetic, Structural and Catalytic studies
Ramón R. S., Gaillard, S., Nun P., Slawin A. M. Z., Nolan S. P. Chem. Eur. J. 2011, 17, 1238-1246.
16) Efficient silver-free gold(I)-catalyzed hydration of alkyne at low catalyst loading.
Nun P., Ramón R. S., Gaillard, S., Slawin A. M. Z., Nolan S. P. J. Organomet. Chem. 2011, 696, 7-11.
15) A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes
Nun P., Gaillard, S., Poater A., Cavallo L., Nolan S. P. Org. Biomol. Chem. 2011, 9, 101-104.
14) Ligand influence in the selective gold-mediated synthesis of allenes
Nun P., Gaillard, S., Slawin A. M. Z., Nolan S. P. Chem. Commun. 2010, 46, 9113-9115.
13) Development of versatile and silver-free protocol for gold(I) catalysis
Gaillard, S., Bosson, J., Ramón R. S., Nun P., Slawin A. M. Z., Nolan S. P. Chem. Eur. J. 2010, 16, 13729-13740.
12) A versatile gold synthon for acetylene C-H bond activation
Fortman G. C., Poater A., Levell J. W., Gaillard, S., Slawin A. M. Z., Samuel D. W., Cavallo L., Nolan S. P. Dalton Trans. 2010, 39, 10382-10390.
11) Expeditious synthesis of [Au(NHC)(L)]+ (NHC=N-Heterocyclic Carbene; L=Phosphine or NHC) complexes
Gaillard, S., Nun, P., Slawin, A. M. Z., Nolan S. P. Organometallics 2010, 29, 5402-5408.
10) Gold-catalyzed Meyer-Schuster Rearrangements: Application to the synthesis of Prostaglandins
Ramón R. S., Gaillard, S., Slawin A. M. Z., Porta A., D’alfonso A., Zanoni G., Nolan S. P. Organometallics 2010, 29, 3665-3668.
9) New dipyridylamine ruthenium complexes for transfer hydrogenation of aryl ketones in water.
Romain, C., Gaillard, S., Elmkaddem M. K., Toupet, L.; Fischmeister C., Thomas C. M., Renaud J. L. Organometallics 2010, 29, 1992-1995.
8) A N-Heterocyclic carbene gold hydroxide complex: A golden synthon
Gaillard, S., Slawin, A. M. Z., Nolan, S. P. Chem. Commun. 2010, 46, 2742-2744.
7) Synthetic and structural studies of [AuCl3(NHC)] complexes.
Gaillard, S., Slawin, A. M. Z., Bonura, A. T., Stevens, E. D. Nolan, S. P. Organometallics 2010, 29, 394-402.
6) Synthesis and characterization of IPrMe-containing silver(I), gold(I) and gold(III) complexes.
Gaillard, S., Bantreil, X., Slawin, A. M. Z., Nolan, S. P. Dalton Trans. 2009, 6967-6971.
5) Recent Development in gold catalysis.
Ramόn R. S., Gaillard, S., Nolan, S. P. Strem Chemiker 2009, 11-20.
4) Iron-Catalyzed Hydrogenation, Hydride Transfer, and Hydrosilylation: An Alternative to Precious-Metal Complexes?
Gaillard, S., Renaud J. L. ChemSusChem. 2008, 1, 505-507.
3) Rapid and Economic Synthesis of New Substituted Amino-Bispyridyl Derivatives via Copper and Palladium Catalysis.
Gaillard, S., Elmkaddem M. K., Fischmeister C., Thomas C. M., Renaud J. L. Tetrahedron Lett. 2008, 49, 3471-3474.
2) Platinum-catalyzed addition of Alkynes to Cycloheptatriene. A Formal Intramolecular [6+2] Cycloaddition.
Tenaglia A., Gaillard, S. Angew. Chem., Int. Ed. 2008, 47, 2454-2457.
1) Ruthenium-Catalyzed Intramolecular Homo-Diels-Alder Reaction of Alkyne-Tethered Norbornadienes. An entry to Fused Angular Triquinanes.
Tenaglia A., Gaillard, S. Org. Lett. 2007, 9, 3607-3610.